Prestressed concrete is a technique that greatly increases loadbearing strengh of concrete beams. The reinforcing steel in the bottom part of the beam, which will be subjected to tensile forces when in service, is placed in tension prior to the concrete being poured around it. Once the concrete has hardened, the tension on the reinforcing steel is released, placing a built in compressive force on the concrete. When loads are applied, the reinforcing steel takes on more stress and the compressive force in the concrete is reduced, but does not become a tensile force. Since the concrete is always under compression, it is less subject to cracking and failure.[3]
Common failure modes of steel reinforced concrete
Reinforced concrete can fail due to inadequate strength, leading to mechanical failure, or due to a reduction in its durability. Corrosion and freeze/thaw cycles may damage poorly designed or constructed reinforced concrete. When rebar corrodes, the oxidation products (rust) expand and tends to flake, cracking the concrete and unbonding the rebar from the concrete. Typical mechanisms leading to durability problems are discussed below.
Reinforced concrete can fail due to inadequate strength, leading to mechanical failure, or due to a reduction in its durability. Corrosion and freeze/thaw cycles may damage poorly designed or constructed reinforced concrete. When rebar corrodes, the oxidation products (rust) expand and tends to flake, cracking the concrete and unbonding the rebar from the concrete. Typical mechanisms leading to durability problems are discussed below.
Mechanical failure
Reinforced concrete can be considered to have failed when significant cracks occur. Cracking of the concrete section can not be prevented; however, the size of and location of the cracks can be limited and controlled by reinforcement, placement of control joints, the curing methodology and the mix design of the concrete. Cracking defects can allow moisture to penetrate and corrode the reinforcement. This is a serviceability failure in limit state design. Cracking is normally the result of an inadequate quantity of rebar, or rebar spaced at too great a distance. The concrete then cracks either under excess loading, or due to internal effects such as early thermal shrinkage when it cures.
Ultimate failure leading to collapse can be caused by crushing of the concrete matrix, when stresses exceed its strength; by yielding of the rebar; or by bond failure between the concrete and the rebar.
Reinforced concrete can be considered to have failed when significant cracks occur. Cracking of the concrete section can not be prevented; however, the size of and location of the cracks can be limited and controlled by reinforcement, placement of control joints, the curing methodology and the mix design of the concrete. Cracking defects can allow moisture to penetrate and corrode the reinforcement. This is a serviceability failure in limit state design. Cracking is normally the result of an inadequate quantity of rebar, or rebar spaced at too great a distance. The concrete then cracks either under excess loading, or due to internal effects such as early thermal shrinkage when it cures.
Ultimate failure leading to collapse can be caused by crushing of the concrete matrix, when stresses exceed its strength; by yielding of the rebar; or by bond failure between the concrete and the rebar.
Carbonation
Rebar for foundations and walls of sewage pump station.
Carbonation, or neutralisation, is a chemical reaction between carbon dioxide in the air with calcium hydroxide and hydrated calcium silicate in the concrete. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5. This highly alkaline environment is one in which the embedded steel is passivated and is protected from corrosion. According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5.[4] The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonate the cement in the concrete from the moment the object is made. This carbonation process will start at the surface, then slowly move deeper and deeper into the concrete. The rate of carbonation is dependent on the relative humidity of the concrete - a 50% relative humidity being optimal. If the object is cracked, the carbon dioxide in the air will be better able to penetrate into the concrete. When designing a concrete structure, it is normal to state the concrete cover for the rebar (the depth within the object that the rebar will be). The minimum concrete cover is normally regulated by design or building codes. If the reinforcement is too close to the surface, early failure due to corrosion may occur. The concrete cover depth can be measured with a cover meter. However, carbonated concrete only becomes a durability problem when there is also sufficient moisture and oxygen to cause electro-potential corrosion of the reinforcing steel.
One method of testing a structure for carbonation is to drill a fresh hole in the surface and then treat the cut surface with phenolphthalein indicator solution. This solution will turn [pink] when in contact with alkaline concrete, making it possible to see the depth of carbonation. An existing hole is no good because the exposed surface will already be carbonated.
Rebar for foundations and walls of sewage pump station.
Carbonation, or neutralisation, is a chemical reaction between carbon dioxide in the air with calcium hydroxide and hydrated calcium silicate in the concrete. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5. This highly alkaline environment is one in which the embedded steel is passivated and is protected from corrosion. According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5.[4] The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonate the cement in the concrete from the moment the object is made. This carbonation process will start at the surface, then slowly move deeper and deeper into the concrete. The rate of carbonation is dependent on the relative humidity of the concrete - a 50% relative humidity being optimal. If the object is cracked, the carbon dioxide in the air will be better able to penetrate into the concrete. When designing a concrete structure, it is normal to state the concrete cover for the rebar (the depth within the object that the rebar will be). The minimum concrete cover is normally regulated by design or building codes. If the reinforcement is too close to the surface, early failure due to corrosion may occur. The concrete cover depth can be measured with a cover meter. However, carbonated concrete only becomes a durability problem when there is also sufficient moisture and oxygen to cause electro-potential corrosion of the reinforcing steel.
One method of testing a structure for carbonation is to drill a fresh hole in the surface and then treat the cut surface with phenolphthalein indicator solution. This solution will turn [pink] when in contact with alkaline concrete, making it possible to see the depth of carbonation. An existing hole is no good because the exposed surface will already be carbonated.
Chlorides
The Paulins Kill Viaduct, Hainesburg, New Jersey, is 115 feet (35 m) tall and 1,100 feet (335 m) long, and was heralded as the largest reinforced concrete structure in the world when it was completed in 1910 as part of the Lackawanna Cut-Off rail line project. The Lackawanna Railroad was a pioneer in the use of reinforced concrete.
Chlorides, including sodium chloride, can promote the corrosion of embedded steel rebar if present in sufficienty high concentration. Chloride anions induce both localized corrosion (pitting corrosion) and generalized corrosion of steel reinforcements. For this reason, only use fresh raw water or potable water for mixing concrete. Insure that the coarse and fine aggregates do not contain chlorides. Do not use admixtures that contain chlorides.
It was once common for calcium chloride to be used as an admixture to promote rapid set-up of the concrete. It was also mistakenly believed that it would prevent freezing. However, this practice has fallen into disfavor once the deleterious effects of chlorides became known. It should be avoided when ever possible.
The use of de-icing salts on roadways, used to reduce the freezing point of water, is probably one of the primary causes of premature failure of reinforced or prestressed concrete bridge decks, roadways, and parking garages. The use of epoxy-coated reinforcing bars and the application of cathodic protection has mitigated this problem to some extent. Properly designed concrete mixtures that have been allowed to cure properly are effectively impervious to the effects of de-icers. (One common problem today is that concrete is allowed to "dry" (dries out) in two to three days by contractors before it cures and thus ultimately develops less than 10% of its design strength).
Another important source of chloride ions is from sea water. Sea water contains by weight approximately 3.5 wt.% salts. These salts include sodium chloride, magnesium sulphate, calcium sulphate and bicarbonates. In water these salts dissociate in free ions (Na+, Mg2+, Cl-, SO42-, HCO3-) and migrate with the water into the capillaries of the concrete. Chloride ions are particularly aggressive for the corrosion of the carbon steel reinforcement bars and make up about 50% of these ions.
The Paulins Kill Viaduct, Hainesburg, New Jersey, is 115 feet (35 m) tall and 1,100 feet (335 m) long, and was heralded as the largest reinforced concrete structure in the world when it was completed in 1910 as part of the Lackawanna Cut-Off rail line project. The Lackawanna Railroad was a pioneer in the use of reinforced concrete.
Chlorides, including sodium chloride, can promote the corrosion of embedded steel rebar if present in sufficienty high concentration. Chloride anions induce both localized corrosion (pitting corrosion) and generalized corrosion of steel reinforcements. For this reason, only use fresh raw water or potable water for mixing concrete. Insure that the coarse and fine aggregates do not contain chlorides. Do not use admixtures that contain chlorides.
It was once common for calcium chloride to be used as an admixture to promote rapid set-up of the concrete. It was also mistakenly believed that it would prevent freezing. However, this practice has fallen into disfavor once the deleterious effects of chlorides became known. It should be avoided when ever possible.
The use of de-icing salts on roadways, used to reduce the freezing point of water, is probably one of the primary causes of premature failure of reinforced or prestressed concrete bridge decks, roadways, and parking garages. The use of epoxy-coated reinforcing bars and the application of cathodic protection has mitigated this problem to some extent. Properly designed concrete mixtures that have been allowed to cure properly are effectively impervious to the effects of de-icers. (One common problem today is that concrete is allowed to "dry" (dries out) in two to three days by contractors before it cures and thus ultimately develops less than 10% of its design strength).
Another important source of chloride ions is from sea water. Sea water contains by weight approximately 3.5 wt.% salts. These salts include sodium chloride, magnesium sulphate, calcium sulphate and bicarbonates. In water these salts dissociate in free ions (Na+, Mg2+, Cl-, SO42-, HCO3-) and migrate with the water into the capillaries of the concrete. Chloride ions are particularly aggressive for the corrosion of the carbon steel reinforcement bars and make up about 50% of these ions.
Alkali silica reaction
Main article: Alkali Silica Reaction
This a reaction of amorphous silica (chalcedony, chert, siliceous limestone) sometimes present in the aggregates with the hydroxyl ions (OH-) from the cement pore solution. Poorly crystallized silica (SiO2) dissolves and dissociates at high pH (12.5 - 13.5) in alkaline water. The soluble dissociated silicic acid reacts in the porewater with the calcium hydroxide (portlandite) present in the cement paste to form an expansive calcium silicate hydrate (CSH). The alkali silica reaction (ASR), causes localised swelling responsible of tensile stress and cracking. The conditions required for alkali silica reaction are threefold: (1) aggregate containing an alkali-reactive constituent (amorphous silica), (2) sufficient availability of hydroxyl ions (OH-), and (3) sufficient moisture, above 75 % relative humidity (RH) within the concrete.[5][6] This phenomenon is sometimes popularly referred to as "concrete cancer". This reaction occurs independently of the presence of rebars: massive concrete structures such as dams can be affected.
Main article: Alkali Silica Reaction
This a reaction of amorphous silica (chalcedony, chert, siliceous limestone) sometimes present in the aggregates with the hydroxyl ions (OH-) from the cement pore solution. Poorly crystallized silica (SiO2) dissolves and dissociates at high pH (12.5 - 13.5) in alkaline water. The soluble dissociated silicic acid reacts in the porewater with the calcium hydroxide (portlandite) present in the cement paste to form an expansive calcium silicate hydrate (CSH). The alkali silica reaction (ASR), causes localised swelling responsible of tensile stress and cracking. The conditions required for alkali silica reaction are threefold: (1) aggregate containing an alkali-reactive constituent (amorphous silica), (2) sufficient availability of hydroxyl ions (OH-), and (3) sufficient moisture, above 75 % relative humidity (RH) within the concrete.[5][6] This phenomenon is sometimes popularly referred to as "concrete cancer". This reaction occurs independently of the presence of rebars: massive concrete structures such as dams can be affected.
Conversion of high alumina cement
Resistant to weak acids and especially sulfates, this cement cures quickly and reaches very high durability and strength. It was greatly used after World War II for making precast concrete objects. However, it can lose strength with heat or time (conversion), especially when not properly cured. With the collapse of three roofs made of prestressed concrete beams using high alumina cement, this cement was banned in the UK in 1976. Subsequent inquiries into the matter showed that the beams were improperly manufactured, but the ban remained.[7]
Resistant to weak acids and especially sulfates, this cement cures quickly and reaches very high durability and strength. It was greatly used after World War II for making precast concrete objects. However, it can lose strength with heat or time (conversion), especially when not properly cured. With the collapse of three roofs made of prestressed concrete beams using high alumina cement, this cement was banned in the UK in 1976. Subsequent inquiries into the matter showed that the beams were improperly manufactured, but the ban remained.[7]
Sulfates
Sulfates (SO4) in the soil or in groundwater, in sufficient concentration, can react with the Portland cement in concrete causing the formation of expansive products, e.g. ettringite or thaumasite, which can lead to early failure of the structure. The most typical attack of this type is on concrete slabs and foundation walls at grade where the sulfate ion, via alternate wetting and drying, can increase in concentration. As the concentration increases, the attack on the Portland cement can begin. For buried structures such as pipe, this type of attack is much rarer especially in the Eastern half of the United States. The sulfate ion concentration increases much slower in the soil mass and is especially dependent upon the initial amount of sulfates in the native soil. The chemical analysis of soil borings should be done during the design phase of any project involving concrete in contact with the native soil to check for the presence of sulfates. If the concentrations are found to be aggressive, various protective coatings can be used. Also, in the US ASTM C150 Type 5 Portland cement can be used in the mix. This type of cement is designed to be particularly resistant to a sulfate attack
Sulfates (SO4) in the soil or in groundwater, in sufficient concentration, can react with the Portland cement in concrete causing the formation of expansive products, e.g. ettringite or thaumasite, which can lead to early failure of the structure. The most typical attack of this type is on concrete slabs and foundation walls at grade where the sulfate ion, via alternate wetting and drying, can increase in concentration. As the concentration increases, the attack on the Portland cement can begin. For buried structures such as pipe, this type of attack is much rarer especially in the Eastern half of the United States. The sulfate ion concentration increases much slower in the soil mass and is especially dependent upon the initial amount of sulfates in the native soil. The chemical analysis of soil borings should be done during the design phase of any project involving concrete in contact with the native soil to check for the presence of sulfates. If the concentrations are found to be aggressive, various protective coatings can be used. Also, in the US ASTM C150 Type 5 Portland cement can be used in the mix. This type of cement is designed to be particularly resistant to a sulfate attack
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