Wednesday, May 19, 2010

Car battery Use and maintenance

Fluid level

Filling a car battery with distilled water
Car batteries using lead-antimony plates would require regular watering top-up to replace water lost due to electrolysis on each charging cycle. By changing the alloying element to calcium, more recent designs have lower water loss unless overcharged. Modern car batteries have reduced maintenance requirements, and may not provide caps for addition of water to the cells. Such batteries include extra electrolyte above the plates to allow for losses during the battery life. If the battery has easily detachable caps then a top-up with distilled water may be required from time to time. Prolonged overcharging or charging at excessively high voltage causes some of the water in the electrolyte to be broken up into hydrogen and oxygen gases, which escape from the cells. If the electrolyte liquid level drops too low, the plates are exposed to air, lose capacity, and are damaged. The sulphuric acid in the battery normally does not require replacement since it is not consumed even on overcharging. Impurities or additives in the water will reduce the life and performance of the battery. Manufacturers usually recommend use of demineralized or distilled water since even potable tap water can contain high levels of minerals.
Charge and discharge
In normal automotive service the vehicle's charging system powers the vehicle's electrical systems and restores charge used from the battery during engine cranking. When installing a new battery or recharging a battery that has been accidentally discharged completely, one of several different methods can be used to charge it. The most gentle of these is called trickle charging. Other methods include slow-charging and quick-charging, the latter being the harshest.
In most cars, the voltage regulator of the charge system is unaware of the relative currents charging the battery and for powering the car's loads such as engine control, fans and lighting. The charge system provides essentially a fixed voltage of typically 13.8 to 14.4 V (Volt), unless the alternator is at its current limit. A discharged battery draws a high current of typically 20 to 40 A (Ampere). As the battery gets charged the charge current decreases to typically 2 A to 5 A. A high load results when multiple high power systems such as radiator fan, heater blowers, lights and entertainment system are running. In this case, the battery voltage will decrease and the charge current as well.
Some manufacturers include a built-in hydrometer to show the state of charge of the battery. This acrylic "eye" has a float immersed in the electrolyte. When the battery is charged, the specific gravity of the electrolyte increases (since all the sulfate ions are in the electrolyte, not combined with the plates), and the colored top of the float is visible in the window. When the battery is discharged (or if the electrolyte level is too low), the float sinks and the window appears yellow (or black). The built-in hydrometer only checks the state of charge of one cell and will not show faults in the other cells. In a non-sealed battery each of the cells can be checked with a portable or hand-held hydrometer. Batteries will last longer if not stored in a discharged state.

Jumper cable connected to battery post. Hydrometer window visible by jumper clamp. White powdery corrosion products visible on top of battery. This BCI Group 24F battery claims 525 cold cranking amperes and 125 minutes reserve capacity.
In emergencies a vehicle can be jump started, by the battery of another vehicle or by a hand portable battery booster.
Whenever the car's charge system is inadequate or too slow to fully charge the battery, a battery charger can be used. Simple chargers will not regulate the charge current and the user needs to stop the process or lower the charge current to prevent excessive gassing of the battery. More elaborate chargers, in particular those implementing the 3-step charge Profile, also referred to as IUoU, charge the battery fully and safely in a short time without requiring user intervention.
Storage
Batteries should be monitored and periodically charged if in storage, to retain their capacity. Batteries intended to be stored should be fully charged, cleaned of corrosion deposits, and left in a cool dry environment. High temperatures increase the self discharge rate and plate corrosion. Lead-acid batteries must always be kept in a fully charged condition. The terminal voltage can be measured as an indication of state of charge. Batteries may be charged periodically by a constant voltage method, or attached to a "float" charger.
Changing a battery
In modern automobiles, the grounding is provided by connecting the body of the car to the negative electrode of the battery, a system called 'negative ground'. In the past some cars had 'positive ground'. Such vehicles were found to suffer worse body corrosion and, sometimes, blocked radiators due to deposition of metal sludge.[citation needed]
When changing a battery, battery manufacturers recommend disconnecting the ground connection first to prevent accidental short-circuits between the battery terminal and the vehicle frame. A study by the National Highway Traffic Safety Association estimated that in 1994 more than 2000 people were injured in the United States while working with automobile batteries.
The majority of automotive lead-acid batteries are filled with the appropriate electrolyte solution at the manufacturing plant, and shipped to the retailers ready to sell. Decades ago, this was not the case. The retailer filled the battery, usually at the time of purchase, and charged the battery. This was a time-consuming and potentially dangerous process. Care had to be taken when filling the battery with acid, as acids are highly corrosive and can damage eyes, skin and mucous membranes. Fortunately, this is less of a problem these days, and the need to fill a battery with acid usually only arises when purchasing a motorcycle or ATV battery.
Recycling
In the United States, about 97% of lead from used batteries is reclaimed for recycling.[6] Many cities offer battery recycling services for lead-acid batteries.
In several U.S. states and Canadian provinces, purchasers of new lead-acid batteries are charged a small deposit fee, refunded when the replaced battery is returned. This encourages recycling of old batteries instead of abandonment or disposal with household waste. Businesses which sell new car batteries may also collect used batteries (and may be required to do so by law) for recycling. Some businesses will accept old batteries on a "walk-in" basis (not in exchange for a new battery). Most battery shops and recycling centers will pay for scrap batteries. This can be a lucrative business, enticing especially to risk-takers because of the wild fluctuations in the value of scrap lead that can occur literally overnight. When lead prices go up, scrap batteries can become targets for thieves.
Freshness
Because of "sulfation", lead-acid batteries stored with electrolyte slowly deteriorate. Car batteries should be installed within one year of manufacture. In the United States, the manufacturing date is printed on a sticker. The date can be written in plain text or using an alphanumerical code. The first character is a letter that specifies the month (A for January, B for February and so on).[7] The letter "I" is skipped due to its potential to be mistaken for the number 1. The second character is a single digit that indicates the year of manufacturing (for example, 6 for 2006). When first installing a newly purchased battery a "top up" charge at a low rate with an external battery charger (available at auto parts stores) may maximize battery life and minimize the load on the vehicle charging system. The top-up charge can be considered complete when the terminal voltage is just above 15.1 V DC. 15 V DC is the voltage level where any sulphation that may be present is driven from the plates back into the electrolyte solution. A new battery can have some sulphation even though it has never been in service. If the top up charge cannot be done it is not harmful to place the battery in immediate service.

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